Structure and thermal decomposition of some 5-(cyclohexyloxy)thianthreniumyl perchlorates

摘要

Five sets of cis- and trans-substituted cyclohexanols were used for reaction with thianthrene cation radical perchlorate, namely, cis- and trans-cyclohexane-1,2-diol, cis- and trans-2-methyl-, 3-methyl-, and 4-methylcyclohexanol, and cis,cis- and trans,trans-3,5-dimethylcyclohexanol. Reaction in CH_2- CI_2 solution and precipitation with ether gave the corresponding crystalline 5-(cyclohexyloxy)- Thianthreniumyl perchlorate salts.