Converting exo-Selective Diels—Alder Reaction to endo-Selective in Chloroloaluminate Ionic Liquids

Anil Kumar; Sanjay S. Pawar

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Converting exo-Selective Diels—Alder Reaction to endo-Selective in Chloroloaluminate Ionic Liquids

机译：在铝铝酸盐离子液体中将外选择性Diels-Alder反应转化为内选择性

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The endo:exo ratio of 0.35:1 for the reaction of cyclopentadiene with methyl methacrylate observed in organic solvents can be converted to 3:1 in chloroaluminate ionic liquids with their effective reuse in Diels-Alder reactions.

机译：在有机溶剂中观察到的环戊二烯与甲基丙烯酸甲酯反应的内消旋比为0.35：1，在氯铝酸盐离子液体中可以有效地重用Diels-Alder反应，将其转换为3：1。

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来源
《The Journal of Organic Chemistry》 |2004年第4期|p.1419-1420|共2页
作者
Anil Kumar; Sanjay S. Pawar;
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作者单位

Physical Chemistry Division, National Chemical Laboratory, Pune 411 008, India;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类有机化学;
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入库时间 2022-08-18 00:03:28

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专利

1. Liquid-Crystalline Ionic Liquids as Ordered Reaction Media for the Diels-Alder Reaction [J] . Bruce Duncan W., Gao Yanan, Canongia Lopes Jose Nuno, Chemistry: A European journal . 2016,第45期

机译：液晶离子液体作为Diels-Alder反应的有序反应介质
2. Understanding exo-selective Diels-Alder reactions involving Fischer-type carbene complexes [J] . Juan Cabrera-Trujillo Jorge, Fernandez Israel Organic & biomolecular chemistry . 2019,第11期

机译：了解涉及Fischer型卡宾络合物的选择性Diels-Alder反应
3. B(C6F5)(3): A New Class of Strong and Bulky Lewis Acid for Exo-Selective Intermolecular Diels-Alder Reactions of Unreactive Acyclic Dienes with alpha,beta-Enals [J] . Zhou Jia-Hui, Jiang Bing, Meng Fei-Fan, Organic letters . 2015,第18期

机译：B（C6F5）（3）：一类新的强而庞大的路易斯酸，用于非反应性无环二烯与α，β-烯醛的Exo选择性分子间Diels-Alder反应
4. Transition Structure Models of Organic Reactions in Chloroaluminate Ionic Liquids: Cyclopentadiene and Methyl Acrylate Diels-Alder Reaction in Acidic and Basic Melts of 1-Ethyl-3-methylimidazolium Chloride with Aluminum(Ⅲ) Chloride [C] . Orlando Acevedo, Jeffrey D. Evanseck, American Chemical Society, Symposium ionic liquids as green solvents: Progress and prospects . 2003

机译：氯铝酸铝离子液体有机反应的过渡结构模型：氯化铝（Ⅲ）氯化铝酸性和碱性熔体中的环戊二烯和丙烯酸甲基丙烯酸甲基丙烯酸甲酯反应
5. Principles of chemical reactivity on the Diels-Alder reaction in ionic liquids and Lewis acid catalysis using large-scale computations. [D] . Acevedo, Orlando. 2003

机译：离子液体中Diels-Alder反应的化学反应性原理和使用大规模计算的路易斯酸催化。
6. The simplest Diels–Alder reactions are not endo-selective [O] . William J. Lording, Thomas Fallon, Michael S. Sherburn, 2020

机译：最简单的Diels-Alder反应不是Endo选择的
7. Converting Exo-selective Diels-Alder Reaction to Endo-selective in the Chloroloaluminate Ionic Liquids [O] . -1

机译：将Exo选择性Diels-ald反应转化为在氯代铝离子液体中的Endo选择性
8. Storing Solar Energy with Liquid Phase Diels-Alder Reactions. Final Report [R] . Poling, B. E. 1983

机译：用液相Diels-alder反应存储太阳能。总结报告

Converting exo-Selective Diels—Alder Reaction to endo-Selective in Chloroloaluminate Ionic Liquids

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