The O-Acylation of Ketone Enolates by Allyl 1H-Imidazole-1-carboxylate Mediated with Boron Trifluoride Etherate—A Convenient Procedure for the Synthesis of Substituted Allyl Enol Carbonates

Barry M. Trost; Jiayi Xu

首页> 外文期刊>The Journal of Organic Chemistry >The O-Acylation of Ketone Enolates by Allyl 1H-Imidazole-1-carboxylate Mediated with Boron Trifluoride Etherate—A Convenient Procedure for the Synthesis of Substituted Allyl Enol Carbonates

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The O-Acylation of Ketone Enolates by Allyl 1H-Imidazole-1-carboxylate Mediated with Boron Trifluoride Etherate—A Convenient Procedure for the Synthesis of Substituted Allyl Enol Carbonates

机译：三氟硼酸乙酯介导的1H-咪唑-1-羧酸烯丙基酯对烯醇酸酯的O-酰化反应—合成烯丙基烯醇碳酸酯的简便方法

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摘要

A convenient access to substituted allyl enol carbonates was established through the reaction of ketone enolates with the complex of allyl lH-imidazole-l-carboxylates and boron trifluoride etherate.

机译：通过酮烯醇化物与烯丙基1H-咪唑-1-羧酸酯和三氟化硼醚化物的配合物反应，可以方便地获得取代的烯丙基碳酸酯碳酸酯。

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来源
《The Journal of Organic Chemistry》 |2007年第24期|p.9372-9375|共4页
作者
Barry M. Trost; Jiayi Xu;
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作者单位

Department of Chemistry, Stanford University, 337 Campus Drive, Stanford, California 94305-5080;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类有机化学;
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1. The O-Acylation of Ketone Enolates by Allyl 1H-Imidazole-l-carboxylate Mediated with Boron Trifluoride Etherate-A Convenient Procedure for the Synthesis of Substituted Allyl Enol Carbonates [J] . Barry M. Trost, Jiayi Xu The Journal of Organic Chemistry . 2007,第24期

机译：三氟硼酸乙酯介导的1H-咪唑-1-羧酸烯丙基酯对烯醇酸酯的O-酰化-合成取代烯丙基烯醇碳酸酯的简便方法
2. Design, synthesis, and applications of potential substitutes of t-Bu-phosphinooxazoline in Pd-catalyzed asymmetric transformations and their use for the improvement of the enantioselectivity in the Pd-catalyzed allylation reaction of fluorinated allyl enol carbonates [J] . Bélanger E., Pouliot M.-F., Courtemanche M.-A., The Journal of Organic Chemistry . 2012,第1期

机译：t-Bu-膦基恶唑啉在Pd催化的不对称转化中的潜在替代物的设计，合成及其应用，及其在改进Pd催化的氟代烯丙基碳酸烯丙酯的Pd烯丙基化反应中对映选择性的应用
3. Zirconium-Mediated Coupling Reactions of Amines and enol or Allyl Ethers:Synthesis of Allyl-and Homoallylamines [J] . Jose Barluenga, Felix Rodriguez, Lucia Alvarez-Rodrigo, Chemistry: A European journal . 2004,第1期

机译：胺与烯醇或烯丙基醚的锆介导偶联反应：烯丙基和高烯丙基胺的合成
4. Boron trifluoride etherate-a mild and inexpensive reagent for synthesis of coumarin derivatives under solvent-free conditions [C] . Gaojun Sun, Zhiyong Wang, Manhua Chen International Conference on Future Materials Engineering and Industry Application . 2012

机译：硼三氟化醚酯 - 一种温和和廉价的试剂，用于在无溶剂条件下合成香豆素衍生物
5. I. Palladium (0)-catalyzed asymmetric rearrangement of allyl enol ether for the synthesis of alpha -aryl quaternary carbon center and II. Synthesis of chiral tryptophan analogs and studies towards synthesis of tryprostatin A and B. [D] . Uddin, Nazim. 2015

机译：I.钯（0）催化的烯丙基烯醇醚的不对称重排，用于合成α-芳基季碳中心和II。手性色氨酸类似物的合成以及对Tryprostatin A和B合成的研究。
6. The O- Acylation of Ketone Enolates by Allyl 1H-imidazole-1-carboxylate Mediated with Boron Trifluoride Etherate---A Convenient Procedure for the Synthesis of Substituted Allyl Enol Carbonates [O] . Barry M. Trost, Jiayi Xu -1

机译：三氟硼酸乙酯介导的1H-咪唑-1-羧酸烯丙基酯对烯醇酸酯的O-酰化反应-合成烯丙基烯醇碳酸酯的简便方法
7. Regio- and Enantioselective Pd-Catalyzed Allylic Alkylation of Ketones through Allyl Enol Carbonates [O] . -1

机译：通过烯丙基烯醇碳酸酯，通过烯丙基烯醇酯的丙酮和对映选择性的PD催化烯丙基烷基化
8. Synthesis of Substituted Cyclopentenones via Boron Trifluoride Mediated Ring Cleavage in Polycyclic Ketones [R] . Marchand, A. P., Vidyasagar, V. 1988

机译：多环酮中三氟化硼介导环裂解合成取代环戊烯酮

The O-Acylation of Ketone Enolates by Allyl 1H-Imidazole-1-carboxylate Mediated with Boron Trifluoride Etherate—A Convenient Procedure for the Synthesis of Substituted Allyl Enol Carbonates

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