SYNTHESIS AND CHARACTERIZATION OF NaY-ENCAPSULATED CuCl_14Pc PREPARED BY CuCl_14Pc-CONTAINING SOLID GEL

摘要

Encapsulating CuCl_14Pc(Pc=phthalocyanine) in the supercage of NaY using CuCl_14Pc-containing aluminosilicate gel is described in this paper. A series of physiochemical characterizations show that CuCl_14Pc is encaged In the cage of NaY and the amount of copper complex encapsulated in NaY By this method is larger than that by other zeolite synthesis methods reported In literature. The encapsulated CuCl_14Pc has much higher catalytic activity in cyclohexane oxidation than the neat complex.