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Ion exchange membrane based on block copolymers. Part III: preparation fo cation exchange membrane

机译:基于嵌段共聚物的离子交换膜。第三部分:阳离子交换膜的制备

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摘要

A new type of ion exchange membrane was investigated for the purpose of applying electrodialysis process. The cation exchange membrane was prepared by sulfonation of the home-made block copolymers of polysulfone (PSf) and polyphenylenesulfidesulfone (PPSS). The lowest measured membrane area resistance, equilbrated in 2 M (mol/dm~3) KCl aqueous solution, was 2.5 Ωcm~2. The cation exchange capacity reached up to 1.9 meq/(g-dry-resin), and the transport number of K~+ was in the 0.77-0.87 range.
机译:为了应用电渗析工艺,研究了一种新型的离子交换膜。通过磺化自制的聚砜(PSf)和聚苯硫醚砜(PPSS)的嵌段共聚物来制备阳离子交换膜。在2 M(mol / dm〜3)KCl水溶液中平衡的最低测得膜面积电阻为2.5Ωcm〜2。阳离子交换容量达到1.9meq /(克干树脂),K〜+的迁移数在0.77-0.87范围内。

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