首页> 外文期刊>Journal of mathematical chemistry >General thermodynamic identities for sensitivity coefficients
【24h】

General thermodynamic identities for sensitivity coefficients

机译:灵敏度系数的一般热力学恒等式

获取原文
获取原文并翻译 | 示例
       

摘要

Expressions are obtained for the sensitivity coefficients partial derivn_i/partial deriv Y of the equilibrium state of a homogeneous multicomponent system in which chemical reactions occur, and in which ideal behavior of the components is not assumed; n_i is the equilibrium amount of the ith chemical species, and Y is a parameter influencing the equilibrium. These thermodynamic identities represent generalizations of the results of the same kind, recently reported for systems with ideal behavior [I. Gutman, I. Fishtik and I. Nagypal, J. Math. Chem. 16 (1994) 229]. Also in the most general case, partial deriv n_i/partial derivY is found to be equal to the sum of contributions originating from certain special equilibria, previously named as Hessian response reactions.
机译:得到了均质多组分系统平衡态的灵敏度系数的部分导出i /部分导出Y的表达式,该均匀多组分系统中发生化学反应,并且其中没有假定组分的理想行为。 n_i是第i个化学物质的平衡量,Y是影响平衡的参数。这些热力学恒等式代表了同类结果的概括,最近报道了具有理想性能的系统[I. Gutman,I。Fishtik和I.Nagypal,J。Math。化学16(1994)229]。同样在最一般的情况下,发现偏导数n_i /偏导数Y等于源自某些特殊平衡的贡献之和,该平衡以前称为Hessian反应。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号