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首页> 外文期刊>Journal of Materials Science >Carbothermal reduction of metal-oxide powders by synthetic pitch to carbide and nitride ceramics
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Carbothermal reduction of metal-oxide powders by synthetic pitch to carbide and nitride ceramics

机译:通过合成沥青将碳氧化物粉末碳热还原为碳化物和氮化物陶瓷

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摘要

The carbothermal reduction potential of mesophase synthetic pitch was investigated. Powders of cobalt oxide, iron oxide, zirconium oxide, manganese oxide, silicon oxide, vanadium oxide, tantalum oxide, tungsten oxide, chromium oxide, and titanium oxide were mixed with pitch and pyrolyzed at a variety of temperatures up to 1500 °C in nitrogen, 5% hydrogen balance argon, and anhydrous ammonia. Pitch was found superior to graphite (and both were superior to charcoal) in carbothermal reactivity by forming carbides and nitrides more completely and at lower temperatures and, in some instances, where no conversion was observed for graphite. It is hypothesized that wetting of the liquid pitch at high temperatures before graphitization leads to better surface contact, and thus, increased kinetics of the carbothermal reduction.
机译:研究了中间相合成沥青的碳热还原势。将氧化钴,氧化铁,氧化锆,氧化锰,氧化硅,氧化钒,氧化钽,氧化钨,氧化铬和氧化钛的粉末与沥青混合并在氮气中在高达1500°C的各种温度下热解,5%的氢气平衡氩气和无水氨。通过在较低温度下更完全地形成碳化物和氮化物,并且在某些情况下未观察到石墨的转化,发现沥青在碳热反应性方面优于石墨(两者均优于木炭)。假设在石墨化之前在高温下润湿液体沥青会导致更好的表面接触,从而提高碳热还原的动力学。

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