Improvement in 1.53-μm-band fluorescence of Er~(3+)/Yb~(3+)-codoped borate glasses based on infrared energy transfer

摘要

Er~(3+)/Yb~(3+)-codoped borate glass consisting of B_2O_3-WO_3-ZnO-Y_2O_3 was synthesized as a potential gain medium for an Er~(3+)-doped fiber amplifier (EDFA). X-ray diffraction (XRD) patterns and Raman spectra were characterized to investigate the structural behavior of the glass host, and absorption spectra were recorded to investigate the spectroscopic properties of the Er~(3+)/Yb~(3+)-codoped borate glasses according to the Judd-Ofelt theory. The 1.53-μm-band emission spectra of Er~(3+) under 980-nm excitation were measured to verify the process of energy transfer (ET) from Yb~(3+) Lo Er~(3+), and the decay lifetimes of Yb~(3+):1020-nm emission were determined to evaluate the ET efficiency (ETE) between Yb~(3+) and Er~(3+). The results indicate that a broad 1.53-μm-band emission occurs for Er~(3+), with a full width at half maximum (FWHM) of approximately 82 nm. Moreover, the emission intensity increases by approximately 66.7% in Er~(3+)/Yb~(3+)-codoped borate glass containing 10.0 mol% Yb~(3+), which is ascribed to the efficiency ETE of Yb~(3+):~2F_(5/2) + ~4I_(15/2)→ Yb~(3+):~2F_(7/2) + Er~(3+):~4I_(11/2). Compared with the previously reported glass systems, the prepared borate glasses have the typical features, including high gain and broad emission at 1.53-μm, which provide a new route to improve the signal gain in the C-band and further develop the short-length optical amplifiers.