Hierarchical flower-like ZnO microstructures: preparation, formation mechanism and application in gas sensor

摘要

Three-dimensional (3D) flower-like ZnO hierarchical microstructures with high uniformity were fabricated from the decomposition of Zn(OH)_4 ~(2−) precursor, which were synthesized by a facile hydrothermal reaction. XRD, FESEM and TEM were employed to characterize the morphology and structure of the products. The as-prepared flower-like ZnO microstructures with an average diameter of about 2 μm are assembled by large amounts of nanosheets, which have a thickness of ~43 nm. The morphology of the ZnO architectures can be tailored by changing hydrothermal conditions, e.g., hydrothermal temperature, reaction time, and concentration of Zn~(2+). On the basis of experimental results, the possible formation mechanism of the flower-like ZnO microstructures was also proposed, and the Zn~(2+) concentration was found to be a vital role in the growth and crystallzation of the flower-like microstructures. The Brunauer-Emmett-Teller measurement shows that the 3D flower-like ZnO hierarchical microstructures possess a specific surface area of about 34.86 m~2/g. Most significantly, the gas sensing test reveals that the sensor made from 3D flower-like ZnO hierarchical microstructures exhibits outstanding gas sensing performance.