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Magnetic heating of silica-coated manganese ferrite nanoparticles

机译:二氧化硅包覆的锰铁氧体纳米粒子的电磁加热

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Manganese ferrite nanoparticles were synthesized using the reverse micelle method; these particles were then coated with silica. The silica-coated nanoparticles were spherical in shape, with an average diameter of 14 nm. The inverse spinel crystalline structure was observed through X-ray diffraction patterns. The coating status of silica on the surface of the nanoparticles was confirmed with a Fourier transform infrared spectrometer. The superparamagnetic properties were revealed by the zero coercive force in the hysteresis curve. Controllable heating at a fixed temperature of 42 ℃ was achieved by changing either the concentration of nanoparticles in the aqueous solution or the intensity of the alternating magnetic field. We found that at a fixed field strength of 5.5 kA/m, the 2.6 mg/ml sample showed a saturation temperature of 42 ℃ for magnetic hyperthermia. On the other hand, at a fixed concentration of 3.6 mg/ml, a field intensity of 4.57 kA/m satisfied the required temperature of 42 ℃.
机译:锰铁氧体纳米粒子采用反胶束法合成。然后用二氧化硅涂覆这些颗粒。二氧化硅涂覆的纳米颗粒为球形,平均直径为14 nm。通过X射线衍射图观察到了尖晶石的逆晶体结构。用傅立叶变换红外光谱仪确认二氧化硅在纳米颗粒表面上的涂覆状态。磁滞曲线中的零矫顽力揭示了超顺磁性。通过改变水溶液中纳米粒子的浓度或交变磁场的强度,可以在42℃的固定温度下实现可控的加热。我们发现,在5.5 kA / m的固定场强下,2.6 mg / ml样品显示的磁热饱和温度为42℃。另一方面,在3.6 mg / ml的固定浓度下,4.57 kA / m的场强满足42℃的要求温度。

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