Pretreatment of anaerobic digestion effluent with ammonia stripping and biogas purification

摘要

In this study, ammonia stripping was optimized for pretreating anaerobic digestion effluent from an anaerobic digestion plant, and the possibility of using CO_2 stripping and biogas injection for adjusting the pH of the effluent before and after the ammonia stripping process was also investigated. For ammonia stripping, the results showed that an overdose of calcium hydroxide, i.e., 27.5 g/L wastewater, achieved higher ammonia, phosphorus, chemical oxygen demand, suspended solids, and turbidity removal efficiency. An air flow rate of 5 L/min for 1L of wastewater was thought as suitable for engineering application. The pH of the anaerobic digestion effluent can be increased from about 7 to about 9 by CO_2 stripping, however which is insufficient for ammonia stripping. For 1L of wastewater treated after ammonia stripping, the pH can be neutralized to about 7 from greater than 11 through biogas injection at 1 L/min for less than 30 min, and continuous injection does not decrease the pH. It was roughly estimated that 43 m~3 of biogas (CH_4:CO_2≈ 60%:40%) produced daily could be purified to CH_4:CO_2 ≈ 74%:26% by neutralizing the pH of the 5 m~3 anaerobic digestion effluent pretreated by ammonia stripping.