Isotherm and kinetic behavior of adsorption of anion polyacrylamide (APAM) from aqueous solution using two kinds of PVDF UF membranes

摘要

To determine the isotherm parameters and kinetic parameters of adsorption of anion polyacrylamide (APAM) from aqueous solution on PVDF ultrafiltration membrane (PM) and modified PVDF ultrafiltration membrane (MPM) is important in understanding the adsorption mechanism of ultrafiltration processes. Effect of variables including adsorption time, initial solution concentration, and temperature were investigated. The Redlich-Peterson equation of the five different isotherm models we chose was the most fitted model, and the R~2 was 0.9487,0.9765 for PM and MPM, respectively;while, the pseudo-first-order model was the best choice among all the four kinetic models to describe the adsorption behavior of APAM onto membranes, suggesting that the adsorption mechanism was a chemical and physical combined adsorption on heterogeneous surface. The thermodynamic parameters were also calculated from the temperature dependence (Δ_rG~θ_m,. Δ_rH~θ_m, Δ_rS~θ_m,), which showed that the process of adsorption is not spontaneous but endothermic process and high temperature favors the adsorption.