Evaluation of the application of dry covers over carbonate-rich sulphide tailings

摘要

In this study, four ten years test areas with covered tailings were geochemically evaluated. Three areas were covered with a fly ash and an overlying sludge layer, and one only with a sludge cover, originating from paper mills. The accumulation of As, Fe and Pb in sludge layers, originating from air-borne dust and the depletion of K, Na and P from both cover layers were observed. High release of elements from tailings was observed in the comparison profile due to oxidation and weathering of tailings. In only sludge covered area, the leaching of elements from tailings decreased. In the profiles with thin ash (20 cm and 30cm), most elements were retained in tailings with pH 7-9. In the profile with the thickest ash (50 cm), elements such as As, Cd, Cu, Mg, Mn, Pb, S and Zn were depleted in the uppermost tailings with pH above 11 and retained deeper in the zone with pH 7-8, which implied that large quantities of fly ash increased the oxidation and weathering of tailings and mobility of elements. Elements excluding K, never reached the groundwater in high concentrations in the covered areas, while the comparison area had high Ca, K, Mn and S concentrations.