Treatment of petroleum wastewater contaminated with hydrocarbons and inorganics by anoxic-aerobic sequential moving bed reactors

摘要

The present study deals with the biotransformation of virulent petroleum refinery concoction with phenol (750 mg/L), emulsified crude oil (300 mgA), S~(2-) (750 mg/L), NH_4~+-N (350 mg/L) and NO_3~--N (1000 mg/L) in anoxic (A1) - aerobic (A2) moving bed reactors operated in series. The efficacy of the system was analysed through measurement of pollutant concentrations, GC-MS and FTIR peaks of the influent and effluent, and biomass activity studies. The system was able to eliminate the organics and inorganics with more than 99% efficiency at 80 h HRT and 64 h cycle time. GC-MS results revealed breakage of high molecular weight organics to smaller compounds after anoxic treatment. Further treatment of anoxic effluent by aerobic biomass reduced the number of peaks in the final effluent significantly. FTIR results were in accord with the GC-MS results. Heterotrophic activity (HA) of the aerobic biomass was higher than anoxic biomass due to its higher free energy change. Anoxic biomass showed chemolithotrophic activity (CA), suggesting survival in the absence of organics. Gas generated from anoxic reactor consisted of 91% nitrogen, 1% CO_2, 1% H_2S and rest was unaccounted.