Hydroxyapatite nanoparticle functionalized activated carbon particle electrode that removes strontium from spiked soils in a unipolar three-dimensional electrokinetic system

摘要

Biohazard performance of Sr radionuclide can be significantly magnified by its release from the contaminated sedimentation. In this study, hydroxyapatite nanoparticle-functionalized activated carbon electrode (AC-HAP) was synthesized and stacked to the cathode compartment of the electrokinetic (EK) system to develop a unipolar three-dimensional (3D) electrochemical process for Sr~(2+) removal from spiked soils. Sr~(2+) adsorption by AC-HAP can be fitted by the pseudo-first-order and pseudo-second-order kinetic models and the Langmuir, Freundlich, and Temkin isotherm models. The largest monolayer adsorption capacity of AC-HAP of 69.49 mg g~(-1) was evaluated in the pH range of 10-12 and at 40 °C. 3D EK further intensified the adsorption process of AC-HAP and the corresponding Sr2* removal from aqueous environments. Voltage gradients and proposing time had a significant effect on the migration and transmission of Sr~(2-) in the electrolyzer. The influence of competitive ions on Sr~(2+) removal in the stock solutions followed A1~(3+) < Mg~(2+) < K~+ < Na~+ < Ca~(2+) while followed A1~(3+) < Na~+ < K~+ < Mg~(2+) < Ca~(2+) in 3D EK. The first three cycles for AC-HAP had taken roughly 50% of the reusability percentage. Sr~(2+) removal from spiked samples in 3D EK was achieved by acid dissolution, electromigration, and selective uptake on particle electrode.