Effective adsorptive removal of Zn~(2+), Cu~(2+), and Cr~(3+) heavy metals from aqueous solutions using silica-based embedded with NiO and MgO nanoparticles

摘要

In this study, the adsorptive removal of Zn~(2+), Cu~(2+), and Cr~(3+) metal ions from aqueous solutions onto NiO-MgO silica-based nanoparticles (SBNs) has been studied. The effect of several factors such as solution pH, initial concentration, contact time, and coexisting ions on the adsorbed amounts of single Zn~(2+), Cu~(2+), and Cr~(3+) ions have been investigated within an array of batch mode experiments. Interestingly, the adsorption of Cr~(3+) at high and low concentrations was very fast, and equilibrium was achieved within 2 min compared to Cu~(2+) and Zn~(2+) which needed 30 and 60 min to reach equilibrium, respectively. The adsorption equilibrium data fitted very well with the Sips adsorption isotherm model for Cu~(2+) and Zn~(2+), and the BET model for Cr~(3+) ions. The maximum uptake was maintained at 7.23,13.76, 41.36 (ions per nm2) for Zn~(2+), Cu~(2+), and Cr~(3+), respectively. This equals to 37.69, 69.68, 209.51 (mg adsorbate per g adsorbent), respectively, showing the promising industrial application of those SBNs. Moreover, the adsorption uptake results increase with increasing the pH in the range of 7.0-11.0 for all investigated metal ions. The thermodynamic parameters such as the changes in Gibbs free energy (△G°), enthalpy (△H°), and entropy (△S°) were determined. The adsorption of Zn~(2+), Cu~(2+), and Cr~(3+) was spontaneous, endothermic, and physical for Cu~(2+) and Cr~(3+), while exothermic and chemical for Zn~(2+). The regeneration and reusability studies have proven that the NiO-MgO SBNs can be employed for the adsorptive of these metals repeatedly without impacting the adsorption capacity indicating their sustainability.