Application of the response surface and desirability design to the Lambda-cyhalothrin degradation using photo-Fenton reaction

摘要

Lambda-cyhalothrin is a potent pyrethroid insecticide used widely in pest management. Detectable levels of the pyrethroid in agricultural watersheds are potentially toxic to aquatic organisms. There is little information in the scientific literature about degradation in aqueous media of the Lambda-cyhalothrin by Advanced Oxidative Process. A mathematical approach for the degradation of this compound has not yet been fully explored... The Central composite design (CCD) and response surface method (RSM) were applied to evaluate and optimize the interactive effects of two operating variables. The initial dosages of H_2O_2 and Fe~(2+) on photo-Fenton degradation of an aqueous solution of Lambda-cyhalothrin in a recirculation flow-through UV photoreactor were used. The remaining concentration of Lambda-cyhalothrin (y_1) and the percentage removal of total organic carbon (3/2) were the monitored factors since they are dependent parameters of y_1 and y_2. According to analysis of variances (ANOVA) results, two proposed models can be used to navigate the design space with regression coefficient R~2 - 0.834 and 0.843 for y_1 and y_2, respectively. A multi-response optimization procedure, based on the global desirability of the factors, was performed to establish the best concentrations of hydrogen peroxide and ferrous sulfate that would allow the most efficient degradation of Lambda-cyhalothrin concomitant with a maximal removal of total organic carbon. The global desirability surface revealed that 0.295 mmol L~(-1) of ferrous sulfate and 3.85 mmol L~(-1) of hydrogen peroxide were close to the optimum conditions to satisfy both factors simultaneously using minimal amounts of reagents. These photo-Fenton conditions promoted 100% of Lambda-cyhalothrin degradation and 79.83% TOC removal (mineralization) in 120 min of reaction time.