The metal influence on the structural chemistry of alkynes: synthetic, spectroscopic and structural studies on magnesium acetylides††Dedicated to Peter A. Williams and his contributions to the Journal of Coordination Chemistry. View all notes

摘要

A family of magnesium acetylides was prepared by treating Bu₂Mg with two equivalents of various alkyne ligands in the presence of different donors. The resulting complexes were examined for the influence of ligand and donors on the spectroscopic and structural properties of the target compounds. The magnesium complexes are compared to the heavier alkaline earth metal analogs. View full textDownload full textKeywordsMagnesium, Alkynes, Donor effects, Alkane elimination, Structure elucidationRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/00958970701732790