Degradation of desphenyl chloridazon in a novel synergetic electrocatalytic system with Ni-Sb-SnO_2/Ti anode and PEDOT/PSS-CNTs modified air diffusion cathode

摘要

This study explored the depth treatment of desphenly chloridazon (DPC) wastewater by a novel synergetic dual-electrodes electrocatalytic (SDEs) system which consisted of Ni-Sb-SnO2/Ti anode (NSSTA) and PEDOT/PSS-CNTs modified activated carbon air diffusion cathode (PP-CNTs AC ADC). NSSTA exhibited an enhanced capability to produce reactive oxygen species (center dot OH and O-3), its O-3 production increased to 6.54 mg/L. PP-CNTs AC ADC was observed to have improved activity of catalyzing oxygen reduction reaction (ORR) with 648.23 mg/L H2O2 generated. Owing to the synergetic effect of O-3 and H2O2, additional center dot OH was obtained in SDEs system through the electro-peroxone reaction. Compared with the single-electrode electrocatalytic (SE) systems, the SDEs system showed superior pesticide degradation performance, higher mineralization current efficiency (MCE) and lower energy consumption (EC). In the SDEs system, the optimal 91.7% of DPC removal efficiency and 90.7% of DPC mineralization efficiency were obtained within 150 min by electrocatalytic oxidation of 17.5 ppm and 25 ppm pesticide wastewater at the current density of 11.94 mA/cm(2), respectively. The treated water showed reduced acute toxicity than that of the raw wastewater, which suggested that the SDEs system is a promising technology for depth treatment of the pesticide industry effluent with simultaneous decontamination and detoxification realized. (C) 2021 Published by Elsevier Ltd.