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A green technology for the preparation of high capacitance rice husk-based activated carbon

机译:一种制备高电容稻壳基活性炭的绿色技术

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摘要

Rice husk (RH) is a kind of biomass with huge amount in the world. Comprehensive utilization of RH is of great significance for a sustainable society. In this paper, a green technology to produce high capacitance rice husk-based activated carbon (RHC) was developed. High capacitance RHC was prepared by KOH activation of RH. The waste liquid produced in the washing procedure of RHC was transformed into nano-SiO2 by acidification with HCl. The KCl saline solution produced from the preparation of nano-SiO2 was used to obtain water via evaporation and prepare KOH via electrolysis. Importantly, the collected water and KOH was reused in this technology. The obtained RHC possessed a specific surface area as high as 3263 m(2) g(-1), and exhibited a high specific capacitance of 330 F g(-1) in 6 mol L-1 KOH aqueous solution. The nano-SiO2 was amorphous with average diameter of similar to 30-40 nm. In addition, the economic analysis demonstrated a significant gross profit margin of 70.72% for the products. The technology is simple, feasible, low-cost and environmentally friendly for large-scale production. (C) 2015 Elsevier Ltd. All rights reserved.
机译:稻壳(RH)是世界上一种数量巨大的生物质。生殖健康的综合利用对社会的可持续发展具有重要意义。本文开发了一种绿色技术,可生产高电容稻壳基活性炭(RHC)。通过RH的KOH活化来制备高电容RHC。 RHC洗涤过程中产生的废液通过用HCl酸化转化为纳米SiO2。由纳米SiO 2的制备产生的KCl盐溶液用于通过蒸发获得水,并通过电解制备KOH。重要的是,所收集的水和KOH已在该技术中重复使用。所获得的RHC具有高达3263 m(2)g(-1)的比表面积,并在6 mol L-1 KOH水溶液中具有330 F g(-1)的高比电容。纳米SiO 2是无定形的,平均直径类似于30-40nm。此外,经济分析表明,这些产品的可观毛利率为70.72%。该技术简单,可行,成本低廉且适合大规模生产。 (C)2015 Elsevier Ltd.保留所有权利。

著录项

  • 来源
    《Journal of Cleaner Production 》 |2016年第1期| 1190-1198| 共9页
  • 作者单位

    Jilin Univ, Coll Chem, Changchun 130012, Jilin Province, Peoples R China;

    Jilin Univ, Coll Chem, Changchun 130012, Jilin Province, Peoples R China;

    Jilin Univ, Coll Chem, Changchun 130012, Jilin Province, Peoples R China|Minist Educ, Key Lab Phys & Technol Adv Batteries, Changchun 130012, Jilin Province, Peoples R China;

    Jilin Univ, Coll Chem, Changchun 130012, Jilin Province, Peoples R China;

    Jilin Univ, Coll Chem, Changchun 130012, Jilin Province, Peoples R China;

    Jilin Univ, Coll Chem, Changchun 130012, Jilin Province, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Green preparation technology; Rice husk; Activated carbon; Supercapacitor; Recycle;

    机译:绿色制备技术;稻壳;活性炭;超级电容器;回收利用;

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