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Efficient Methods for Calculations of Compressibility, Density, and Viscosity of Natural Gases

机译:计算天然气可压缩性,密度和粘度的有效方法

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摘要

This study presents two new methods for calculating the properties of natural gases. The first is an efficient empirical model to calculate compressibility and density of natural gases containing high amounts of heptane plus and non-hydrocarbon components. The model is derived from 2,400 measurements of compressibility and density of various gases presented in this study. Accuracy of the model is compared to various equations of state (EOS), corresponding state, and empirical methods. The study shows that the new model is simpler and more efficient than EOS. It eliminates the numerous computations involved in EOS calculations. The new method also eliminates the characterization of the heptane plus fraction and estimation of binary interaction parameters needed for EOS calculations. Experimentally measured densities of several gases have been used to study the validity of the proposed method. These measurements indicate that the new method successfully captures the physical trend of changing gas density as a function of pressure, temperature, and composition. The second method is a modification of the Lee-Gonzalez-Eakin gas viscosity correlation. The new method accounts for the presence of heptane plus, hydrogen sulfide, and carbon dioxide in natural gases. The proposed method is compared to other EOS-based viscosity models, corresponding state methods, and correlations. The comparison indicates the superiority of the new method over other methods used to calculate the viscosity of natural gases.
机译:这项研究提出了两种计算天然气特性的新方法。第一个是一个有效的经验模型,用于计算包含大量庚烷以及非烃成分的天然气的可压缩性和密度。该模型源自本研究中提出的2400种可压缩性和各种气体密度的测量值。将模型的准确性与各种状态方程(EOS),相应的状态和经验方法进行比较。研究表明,新模型比EOS更简单,更有效。它消除了EOS计算中涉及的大量计算。新方法还消除了庚烷加馏分的表征以及EOS计算所需的二元相互作用参数的估计。实验测量的几种气体的密度已被用来研究该方法的有效性。这些测量结果表明,新方法成功地捕获了随压力,温度和成分变化而变化的气体密度的物理趋势。第二种方法是修改Lee-Gonzalez-Eakin气体粘度相关性。新方法说明了天然气中存在庚烷,硫化氢和二氧化碳。将该方法与其他基于EOS的粘度模型,相应的状态方法和相关性进行了比较。比较结果表明,该新方法优于用于计算天然气粘度的其他方法。

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