Influence of Al/Er ratio on the optical properties and structures of Er~(3+)/ Al~(3+) co-doped silica glasses

摘要

In this study, Er~(3+)/Al~(3+) co-doped silica glasses with various Al/Er ratios ranging from 0 to 200 and a constant Er_2O_3 amount were prepared using the sol-gel method combined with high-temperature vacuum sintering. The absorption, emission spectra, and fluorescence lifetime of Er~(3+) ions were recorded and the absorption and emission cross sections were calculated. Using Raman, ~(27)Al and ~(29)Si magic angle spinning nuclear magnetic resonance (MAS-NMR), ~(27)Al triple-quantum (TQ)-MAS-NMR, and electron paramagnetic resonance (EPR) spectroscop-ies, the physical and optical properties were correlated with the glass structural modifications due to the Al/Er ratio change. With the increase in the Al/Er ratio, the content of Al~(3+) ions around the Er~(3+) ions gradually increased. Meanwhile, the AlO_5 and AlO_6 polyhedrons increased at the expense of the AlO_4 and SiO_4 tetrahedrons, which resulted in an improved symmetry and better ionic Er-O bonds. These structural changes led to the site-to-site variations in the Er~(3+) local environment and the changes in the ligand field strength of the Er-O bonds. This, in turn, resulted in the inhomogeneous broadening of the absorption and emission spectra, with a blue shift of both absorption and emission peaks and a decrease in both absorption and emission at 1.53μm. With the increase in Al/Er ratio, the full width at half maximum (FWHM) of the emission increased from 27.2 to 54.3 nm. The FWHM × emission cross section (σ_(emi)) parameter for evaluating broadband amplification behavior was 30.1 × 10~(-20)cm~2•nm. This work reveals the close relationship between the glass structure and the spectroscopic properties of Er~(3+) ions and provides an important reference for the design of broadband amplifier materials in the field of optical communication.