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Co-doped anatase TiO_2 nanofibers fabricated by electrospinning

机译:电纺制共掺杂锐钛矿型TiO_2纳米纤维

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摘要

Co-doped TiO_2 nanofibers with an average diameter of ~70 nm were fabricated with electrospinning method. X-ray diffraction measurements show that the nanofibers possess pure anatase structure. The obtained nanofibers exhibit evident room temperature ferromagnetism through magnetic measurement. The photoluminescence of the Co-doped TiO_2 nanofibers is composed of two emission bands attributed to self-trapped excitons and oxygen vacancies, different from that of pure TiO_2 nanofibers which only includes emission due to self-trapped excitons. Photoluminescence intensity due to oxygen vacancies vary with annealing atmosphere and Co concentration, and the ferromagnetic moment increases with the increment of oxygen vacancies.
机译:采用静电纺丝法制备了平均直径约70nm的共掺杂TiO_2纳米纤维。 X射线衍射测量表明,纳米纤维具有纯的锐钛矿结构。通过磁性测量,获得的纳米纤维表现出明显的室温铁磁性。共掺杂的TiO_2纳米纤维的光致发光由两个发射带组成,这两个发射带归因于自捕获的激子和氧空位,与纯TiO_2纳米纤维的光致发光仅包括由于自捕获的激子引起的发射。氧空位引起的光致发光强度随退火气氛和Co浓度的变化而变化,铁磁矩随氧空位的增加而增加。

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