Electrocatalytic Reactivity of Zeolite-Encapsulated Co(salen) with Benzyl Chloride

摘要

While electrochemical techniques have not (yet) proved definitive in terms of identifying the actual coordination environment of zeolite-encapsulated transition metal complexes, electrocatalysis with {Co}salen)} NaY has shown that the physicochemical environment of the zeolite leads to 1000-fold increases in reactivity and that the effects of site isolation on the heterogeneous catalyst contribute to an increase in catalyst life of at least 200/100.