Formation of Iminium (C=NH_2) Species from Cyanogen (C_2N_2) and Hydrogen on Pt(111)

摘要

Fourier transform reflection-absorption infrared spectroscopy(FT-RAIRS) was used to study the chemistry of cyanogens (C_2N_2) and hydrogen on Pt(111). The partial dissociative adsorption of cyanogens at 300 K results in the formation of the well-known molecularly adsorbed α state and dissociatively adsorbed β_1 and β_2 states.