New Metalloporphyrins with Extremely Altered Redox Properties: Synthesis, Structure, and Facile Reduction to Airπ-Stable -Anion Radicals of Zinc and Nickel β-Heptanitroporphyrins

摘要

In conclusion, the aforementioned selective access to TDCP- (NO_2)_7P opens the way to a series of metalloporphyrins with drastically altered redox properties and, thus, with potential applications in electrochemistry, organic chemistry, and cataly- sis.