Bimetallic Magnetic Material [Ni(diamine)_2]_2[Fe(CN)_6]X with Two-Dimensional Network Extended by Fe(Ⅲ)-CN-Ni(Ⅱ) Linkages

摘要

Cyanide-bridged bimetallic assemblies [Ni(pn)_2])2[Fe(CN)_6]x .catnH_2O (X=ClO_4~- and n=2(1); X= BF_4~- and n=2 (2); X=PF_6~- and n=2 (3)) and [Ni(1, 1-dmen)_2]_2[Fe(CN)_6]X .nH_2O(X=ClO_4~- and n=2 (4); X=BF_4~- and n=3 (5); X=PF_6~- and n=2 (6); X=CF_3SO_3~- and n=2 (7); X=BzO~- and n=6 (8); X= I~- and n=4 (9); X=N_3~- and n=4 (10); X=NCS~- and n=1 (11); X=NO_3~- and n=4 (12)) have been prepared (pn=1, 2-propanediamine, 1, 1-dmen=1, 1-dimethylethylenediamine).