Characterization of ultrafine particle number concentration and size distribution during a summer campaign in southwest Detroit

摘要

This paper presents results from a study conducted in southwest Detroit from July 20 to July 30, 2002, to characterize ambient ultrafine particles (d(p) < 0.1 mum), and to examine the effect of local sources and meteorological parameters on the ultrafine number concentration and size distribution. The number concentrations of ambient particles in the size range of 0.01-0.43 mum were obtained from a scanning mobility particle sizer (SMPS). Meteorological parameters including ambient temperature, relative humidity, wind speed, wind direction, rainfall, and solar radiation flux were also monitored concurrently atop a 10-m tower. On average, ultrafine particles ranged from 1.4 X 10(4) to 2.5 X 10(4) cm(-3), with significant diurnal and daily variations, and accounted for similar to89% of the total number concentration (0.01 < d(p) < 0.43 mum) Time-series plots of the 5-min number concentrations revealed that peak concentrations often occurred during morning rush hour and/or around solar noon when photochemical activity was at a maximum. The morning traffic-related peak coincided with the NOx peak, whereas the photochemical-related peak correlated with solar radiation flux. On some days, the noon peak concentration was many times higher than the morning peak concentration. Although the number, size distribution varied considerably over the course of the study, it typically exhibited one to three modes, with diameters around 0.01, 0.05, and 0.09 mum. Analysis of the influence of wind direction indicated that stationary sources could be one of the contributors to elevated ultrafine particle concentration. Overall, the data indicated that fossil fuel combustion and atmospheric gas-to-particle conversion of precursor gases are the major sources of ultrafine particles in the southwest Detroit area during the summer.