Effects of Boride Former Elements on Recovery and Recrystallization of Reverse-transformed Austenite in Fe-19%Ni Alloy

摘要

Effects of various boride former elements (Ta, W, Nb, Ti, Mo) and/or B on recovery and recrystallization of reverse-transformed austenite were examined in carbon-free Fe-19mass%Ni alloys. The combined addition of Nb and B was found to be the most effective in suppressing them; the recrystallization temperature of the reverse-transformed austenite rose up to 1 200 K which is ～ 100 K higher than that of alloys with single addition of boride former element or B. TEM observation of extraction replicas indicated that the retardation of recovery and recrystallization was due to very fine precipitates of Nb-boride. It was made clear from the theoretical analysis on the solubility product of several MB_2-type borides (M = Cr, Mn, Nb, Ti, Mo) that NbB_2 was the most stable over a wide range of temperature (773-1 173 K). This may be the reason why recovery and recrystallization do not occur up to the highest temperature in case of the combined addition of Nb and B.