首页> 外文期刊>International Journal of Microstructure and Materials Properties >Book Review: Vibrational Spectroscopy of Polymers: Principles and Practice by N.J. Everall,J.M. Chalmers and P.R. Griffiths
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Book Review: Vibrational Spectroscopy of Polymers: Principles and Practice by N.J. Everall,J.M. Chalmers and P.R. Griffiths

机译:书评:聚合物振动光谱法:原理与实践,作者:N.J。Everall,J.M。查尔默斯和格里菲斯

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For many decades vibrational spectroscopy has occupied a prominent position at the heartland of applied and fundamental polymer research. Vibrational spectroscopy has had and continues to have, a vital impact in areas ranging from fundamental studies of polymer structure through to the control of manufacturing processes. This is despite the fact that, from a fundamental perspective, infrared (IR) or Raman spectroscopy might not be considered to be the 'best' technique per se for tackling a particular problem. For example, the detailed analysis of polymer tacticity, branching, sequence and end-groups would usually be more readily achieved via a combination of nuclear magnetic resonance (NMR) and matrix-assisted laser desorption ionisation mass spectrometry (MALDI-MS), while a fundamental understanding of crystallinity and orientation is more easily obtained using X-ray diffraction (XRD).
机译:几十年来,振动光谱在应用和基础聚合物研究的核心领域占据着重要地位。振动光谱在从聚合物结构的基础研究到制造过程的控制等各个领域都具有并将继续产生至关重要的影响。尽管有这样一个事实,从根本上讲,红外(IR)或拉曼光谱法可能并不被认为是解决特定问题的“最佳”技术。例如,通常通过结合核磁共振(NMR)和基质辅助激光解吸电离质谱(MALDI-MS)可以更轻松地完成聚合物的立构规整度,支链,序列和端基的详细分析。使用X射线衍射(XRD)更容易获得对结晶度和取向的基本了解。

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