Byproducts and reaction pathways for integration of the Cu-Cl cycle of hydrogen production

摘要

The impact of exit streams containing byproducts of incomplete reactions in an integrated thermochemical copper—chlorine (Cu—Cl) cycle of hydrogen production is studied in this paper. In the hydrolysis reaction, CuCl_2reacts with steam to produce solid copper oxy-chloride. If the hydrolysis reaction does not proceed to completion, particles of un-reacted CuCl_2 will be transferred to a downstream molten salt reactor where oxygen is released from copper oxychloride decomposition. Undesirable chlorine may also be released as a result of CuCl_2 decomposition together with oxygen, resulting in a mass imbalance of the overall cycle. This paper also examines the implications of incomplete hydrolysis reactions on the kinetics and thermodynamics of the oxygen reactor in the Cu-Cl cycle, specifically the spontaneity of CuCl_2 decomposition and parameters that minimize the release of chlorine. Theoretical analysis of the decomposition of a mixture of CuO and CuCl_2 is also performed in this paper. It is found that usage of copper oxychloride is preferable over a mixture of CuCl_2 and CuO in the oxygen production reaction of the Cu—Cl cycle.