Optimization of activated carbons for hydrogen storage

摘要

Activated carbons (ACs) having hydrogen storage performances among the highest reported so far (i.e. 6.6 wt. % at 77 K and 4 MPa) are presented. These materials were prepared by chemical activation of anthracite with KOH. The effects of two experimental parameters: KOH/anthracite weight ratio (W) and activation temperature (T), on the hydrogen storage capacity were studied by application of central composite design and response surface methodology. A quadratic model was developed for correlating W and 1 to the hydrogen storage capacity. The analysis of variance showed that W the onlj significant parameter in the range of the experimental conditions tested. Our optimized AC showed higher hydrogen capacity in terms of absolute and excess storage properties than the well-known MAXSORB-3.