Experimental investigation and theoretical modeling of dehydriding process in high-pressure metal hydride hydrogen storage systems

摘要

This study explores the endothermic dehydriding (desorption) reaction that takes place in a high-pressure metal hydride (HPMH) hydrogen storage system when hydrogen gas is released to the fuel cell. The reaction is sustained by circulating warm fluid through a heat exchanger embedded in the HPMH powder. A systematic approach to modeling the dehydriding process is presented, which is validated against experimental data using two drastically different heat exchangers, one using a modular tube-fin design and the other a simpler coiled-tube design. Experiments were performed inside a 101.6-mm (4-in) diameter pressure vessel to investigate the influences of hydrogen release rate, heat exchanger fluid flow rate and fluid temperature on the dehydriding process for the HPMH Ti_(1.1)CrMn. It is shown the dehydriding reaction rate can be accelerated by increasing the fluid temperature and/or the rate of pressure drop. HPMH particles located in warmer locations close to heat exchanger surfaces both began and finished dehydriding earlier than particles farther away. 2-D and 3-D models were created in Fluent to assess the dehydriding performances of the modular tube-fin heat exchanger and coiled-tube heat exchanger, respectively. The models are shown to be quite accurate at predicting the spatial and temporal variations of metal hydride temperature during the dehydriding reaction.