Studies on elements diffusion of Mn/Co coated ferritic stainless steel for solid oxide fuel cell interconnects application

摘要

The spinel structure of manganese cobalt oxide (Mn,Co)_3O_4 is one of the most promising coatings for solid oxide fuel cell (SOFC) stainless steel interconnects. The stoichiometric Mn_91.5)Co_(1.5)O_4 composition has properties that are preferable to other Mn/Co ratios, for example a higher conductivity and a thermal expansion coefficient that matches the typical steel substrate. However, previous work showed the Mn/Co ratio changes during operation due to the diffusion of Mn from the substrate. The results presented here are on three coatings with different compositions (namely; pure Co, Mn_(20)Co_(80), and Mn_(40)Co_(60)) with each coating composition deposited to a thickness of 800 nm, 1500 nm, and 3000 nm. The coatings were applied by DC magnetron sputtering and then machine cut into coupons for isothermal annealing at 800℃ in air using a batch-type furnace for 2, 10, 50, 250, and 1000 h. The morphology, chemical composition (including surface and cross sections of the layers) and structures of the oxides formed were analyzed by SEM, EDS and XRD. Analysis of the element diffusion (Mn, Co, Cr, Fe) shown here points to an optimized coating recipe of Mn_(40)Co_(60).