Phase-structural transformations in a metal hydride battery anode La1.5Nd0.5MgNi9 alloy and its electrochemical performance

摘要

This work was aimed at in situ studies of the phase-structural transformations in an Mg and Nd-modified LaNi3 intermetallic having a bulk composition La1.5Nd0.5MgNi9, as related to its performance,as battery anode material in the Ni-Metal Hydride batteries. The interactions in the La1.5Nd0.5MgNi9 system were studied by in situ neutron diffraction in a temperature range 300-1248 K. Two alternative processes of preparation of the alloy were studied: (a) Synthesis from a mixture of the powders La0.75Nd0.25Ni5 + La0.75Nd0.25MgNi4; and (b) annealing of the alloy prepared by induction melting. Various transformations take place in the samples on heating, leading to the formation of four new phases, all with the stacking structures of the intermetallic alloys having three variable ratios (RE + Mg)/Ni, 1:3, 2:7 and 5:19. Further to (La0.75Nd0.25)(2)MgNi9 with a rhombohedral PuNi3 type, there were formed (La0.75Nd0.25)(3)MgNi14 with a rhombohedral Gd2Co7 structure and two polymorphic modifications of (La0.75Nd0.25)(4)MgNi19 compound, a high temperature hexagonal Pr5Co19 type and a low temperature rhombohedral Ce5Co19 type. In every case the unit cell parameters showed shrinking as compared to the La-based analogues. Nd substitution for La in La2MgNi9 promotes the formation of a more homogeneous alloy, with a predominant formation of the target AB(3) intermetallic.