One-pot hydrothermal synthesis of CdS/NiS photocatalysts for high H-2 evolution from water under visible light

摘要

The development of efficient and stable noble-metal-free photocatalysts is crucial for hydrogen evolution from water splitting as clean energy. This study reports uniform CdS/NiS spherical nanoparticles through a simple one-pot hydrothermal method with the aid of KOH. The prepared CdS/NiS composites show superior photocatalytic activities toward the water splitting under visible light. A suitable amount of KOH in the synthesis benefits to form CdS/NiS photocatalysts with the improved activity. The CdS/NiS composite including 10 mol % metal percentage of Ni exhibits the highest photocatalytic activity. The high hydrogen evolution rate of 24.37 mmol h(-1) g(-1) is achieved over the CdS/NiS composite photocatalyst. The CdS/NiS photocatalyst has good photocatalytic stability in the recycling uses. The present CdS/NiS as a noble-metal-free photocatalyst provides the superior visible-light driven catalytic activity for hydrogen evolution. (C) 2017 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.