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Development of a hydrogen dual sensor for fuel cell applications

机译:开发用于燃料电池的氢双传感器

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摘要

The development and application of a hydrogen dual sensor (HDS) for the application in the fuel cell (FC) field, is reported. The dual sensing device is based on a ceramic platform head with a semiconducting metal oxide layer (MOx) printed on Pt interdigitated contacts on one side and a Pt serpentine resistance on the back side. MOx layer acts as a conductometric (resistive) gas sensor, allowing to detect low H-2 concentrations in air with high sensitivity and fast response, making it suitable as a leak hydrogen sensor. The proposed Co-doped SnO2 layer shows high sensitivity to hydrogen (R-0/R = 90, for 2000 ppm of H-2) at 250 degrees C in air, and with fast response (3 s). Pt resistance serves as a thermal conductivity sensor, and can used to monitor the whole range of hydrogen concentration (0-100%) in the fuel cell feed line with short response-recovery times, lower than 13 s and 14 s, respectively. The effect of the main functional parameters on the sensor response have been evaluated by bench tests. The results demonstrate that the dual sensor, in spite of its simplicity and cheapness, is promising for application in safety and efficiency control systems for FC power source. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:报道了氢双传感器(HDS)在燃料电池(FC)领域中的开发和应用。该双传感设备基于陶瓷平台头,该半导体平台头的一侧印有Pt叉指触点上的半导体金属氧化物层(MOx),背面则印有Pt蛇形电阻。 MOx层用作电导(电阻)气体传感器,允许以高灵敏度和快速响应检测空气中的低H-2浓度,使其适合用作泄漏氢传感器。拟议中的Co掺杂SnO2层在250摄氏度的空气中显示出对氢的高灵敏度(R-0 / R = 90,对于2000 ppm的H-2),并且响应速度快(<3 s)。 Pt电阻用作热导率传感器,可用于以较短的响应恢复时间(分别低于13 s和14 s)监测燃料电池进料管线中氢浓度的整个范围(0-100%)。主要功能参数对传感器响应的影响已通过基准测试进行了评估。结果表明,双传感器尽管简单,便宜,但仍有望在FC电源的安全和效率控制系统中应用。 (C)2018氢能出版物有限公司。由Elsevier Ltd.出版。保留所有权利。

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