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Numerical simulation of hydrogen production by gasification of large biomass particles in high temperature fluidized bed reactor

机译:大型流化床反应器中大生物质气化制氢的数值模拟

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Biomass as a renewable fuel compared to fossil fuels usually contains high moisture content and volatile release. Hydrogen production by large particle biomass gasification is a promising technology for utilizing high moisture content biomass particle in the high temperature fluidized bed reactor. In the present work, simulation of large particles biomass gasification investigated at high temperature by using the discrete phase model (DPM). Combustible gases with homogeneous gas phase reactions, drying process with a heterogeneous reaction, primary and secondary pyrolysis with independent parallel reaction by using two-competing-rate model to control a high and low temperature were used. During the thermochemical process of biomass, gaseous products containing of H-2, H2O, CH4, CO and CO2 was obtained. The effects of concentration, mole and mass fraction and hydrodynamics effects on gaseous production during gasification were studied. The results showed that hydrodynamic effect of hot bed is different from cold bed. Concentration and molar fraction of CO and H-2 production by continually and stably state and small amount of CO2, H2O, and CH4 was obtained. The hydrodynamic of bed plays the significant role on the rate of gaseous products. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:与化石燃料相比,生物质作为可再生燃料通常包含高水分含量和挥发性释放物。大颗粒生物质气化制氢是在高温流化床反应器中利用高水分生物质颗粒的有前途的技术。在本工作中,通过使用离散相模型(DPM)在高温下研究了大颗粒生物质气化的模拟。通过采用二竞争速率模型控制高温和低温,使用具有均相气相反应的可燃气体,具有异相反应的干燥过程,具有独立平行反应的一次和二次热解。在生物质的热化学过程中,获得了含有H-2,H2O,CH4,CO和CO2的气态产物。研究了气化过程中浓度,摩尔和质量分数以及流体动力学对气体产生的影响。结果表明,热床的水动力效应与冷床不同。通过连续稳定的状态获得少量的CO2,H2O和CH4,从而获得了CO和H-2的浓度和摩尔分数。床的流体动力学对气态产物的速率起重要作用。 (C)2017氢能出版物有限公司。由Elsevier Ltd.出版。保留所有权利。

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