Facile synthesis of molybdenum-based layered double hydroxide nanorods for boosting water oxidation reaction

摘要

Exploiting environmentally friendly and robust oxygen evolution reaction (OER) electrodes is still a great difficulty to promote the water oxidation for electrocatalytic water splitting. In the work, molybdenum-doped nickel copper hydrotalcite (NiCuMox LDH) nanoarrays have been firstly in situ grown on nickel foam (NF) via a typical hydrothermal process. When NiCuMo0.2 LDH/NF was used as a OER electrocatalyst, it displays superior electrocatalytic performance with the need of small overpotentials of only 290 mV to drive 40 mA cm(-2) and a low Tafel slope of 39.8mVdec(-1), which are almost one of the best water oxidationactivities reported so far. The enhanced electrocatalytic performance is attributed to unique urchin-like structure, more exposure to active sites and enhanced charge transfer rate owing to the synergistic effect of Mo doping and NiCu LDH. The work put forward a new method for the development of efficient water oxidation electrocatalysts, which will fill the gap for the exploitation of trimetal LDH-based electrodes in large-scale water splitting applications in the future. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.