Facile fabrication of nickel/porous g-C_3N_4 by using carbon dot as template for enhanced photocatalytic hydrogen production

摘要

Ni/porous g-C3N4 was prepared by high temperature thermal polymerization process using carbon dots as soft template and photodeposition. With nickel nanoparticles supported as co-catalyst, the hydrogen evolution reaction (HER) activity of the photocatalyst has been significantly enhanced under visible light, which is up to 1273.58 mmol g(-1) h(-1), superior to pristine g-C3N4 (4.12 mmol g(-1) h(-1)). This is attributed to the inhibited recombination of photogenerated electron-hole pairs and the much better electron transport efficiency. The formed porous structure of carbon nitride could facilitate light utilization and together with nickel nanoparticles, better charge separation can be realized which are proved by the photoluminescence, time-resolved photoluminescence spectra, transient photocurrent measurements and electrochemical impendence spectroscopy. This work provides a useful route to obtain less expensive and efficient photocatalyst containing no noble metals for hydrogen production. (c) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.