Dynamic simulation and control of solar biomass gasification for hydrogen-rich syngas production during allothermal and hybrid solar/autothermal operation

摘要

Solar biomass steam gasification using concentrated sunlight offers an efficient means of storing intermittent solar energy into renewable solar fuels while upgrading the carbonaceous feedstock. Such solar-driven (allothermal) processes have demonstrated the ability and the effectiveness for the production of high quality hydrogen-rich syngas, but they suffer from inherent barriers related to the variability of solar energy caused by cloud passages and shut off at night. The concept of hybrid solar/autothermal gasification appears promising to meet the requirement for stable and continuous operation under fluctuating or intermittent solar irradiation. To date, dynamic modelling to simulate coupled solar/combustion heating and steam gasification using real solar irradiation data has never been proposed and could be used to predict the annual performance of large-scale solar gasification plants. In this study, a dynamic mathematical model of a scaled-up solar gasification reactor was developed. The model was composed of a system of differential equations that were derived from unsteady mass and energy conservation equations. After an experimental validation step with the results from a lab-scale solar reactor, the dynamic model was applied at large scale to determine the reactor temperature and syngas production evolution during continuous day and night operation in both solar-only (allothermal) and hybrid solar/autothermal modes. Different reactants feeding management strategies were proposed and compared with the aim of achieving enhanced syngas productivity and optimized use of solar energy during solar-aided steam gasification. It was shown that the hybrid mode with partial oxy-combustion of the feedstock and dynamic feeding control results in the most stable process operation upon fluctuating solar power input, while ensuring continuous production of H-2 and CO at night and during cloudy periods. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.