Development of a Fe/Mg-bearing metallurgical waste stabilized-CaO/NiO hybrid sorbent-catalyst for high purity H_2 production through sorption - enhanced glycerol steam reforming

摘要

In this work, a Fe/Mg-bearing metallurgical waste (upgraded slag oxide, UGSO) was, for the first time, investigated as a stabilizer for increasing the cyclic stability of CaO-based sorbents. The sorbents were prepared through the wet mixing of the ball-milled UGSO particles with the limestone-derived calcium citrate under sonication. The sorption capacity of samples containing different waste loadings (5, 10, 15, and 25 wt%) was studied for 18 carbonation/regeneration cycles under conditions similar to the sorption-enhanced glycerol steam reforming process. A significant improvement of the cyclic stability was observed for all doped sorbents; however, the sample with 10 wt% UGSO showed the highest sorption capacity among all tested samples. This optimum sorbent was further used to synthesize a UGSO stabilized CaO-NiO hybrid sorbent-catalyst material (20 wt% NiO loading), whose performance was tested in sorption-enhanced steam reforming of glycerol. A H-2 purity of around 95% was obtained in the pre-breakthrough period that lasted for about 30 min. In summary, the results showed a better stability of UGSO stabilized sorbents compared to pure CaO and a good performance of the CaO-UGSO10/NiO sorbent-catalyst hybrid material in the sorption-enhanced reforming process. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.