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Effect of thermal cycling on durability of a solid oxide fuel cell stack with external manifold structure

机译:热循环对外歧管结构固体氧化物燃料电池堆耐久性的影响

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摘要

A 5-cell stack with external manifold is thermal cycled between room temperature and 750 degrees C fifteen times. The electric performances after each cycle are measured and compared. The stack has an initial peak output of 328.44 W and shows excellent stability in thermal cycling. The average operating voltage degradation rate is only 0.8% corresponding each thermal cycle. A cell from the stack is randomly chosen for electrochemical evaluation. Its performance is found to be comparable to a cell which is not thermal cycled. Post-test examination shows deterioration of cathode contact materials at points of contact and cracks throughout the oxide layer between corrugated and bipolar plates to be the main causes of the degradation. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:具有外歧管的5个单元叠层在室温和750摄氏度之间进行热循环。测量每个循环后的电动性能并进行比较。堆叠具有328.44W的初始峰值输出,并在热循环中显示出优异的稳定性。平均工作电压劣化率仅为每次热周期0.8%。来自堆叠的电池被随机选择用于电化学评估。发现其性能与不热循环的细胞相当。测试后检查显示阴极接触材料的劣化在瓦楞和双极板之间的氧化物层的接触点处的裂缝,以成为降解的主要原因。 (c)2020氢能源出版物LLC。 elsevier有限公司出版。保留所有权利。

著录项

  • 来源
    《International journal of hydrogen energy》 |2020年第35期|17927-17934|共8页
  • 作者单位

    Huazhong Univ Sci & Technol Sch Mat Sci & Engn State Key Lab Mat Proc & Die & Mould Technol Wuhan 430074 Hubei Peoples R China;

    Huazhong Univ Sci & Technol Sch Mat Sci & Engn State Key Lab Mat Proc & Die & Mould Technol Wuhan 430074 Hubei Peoples R China;

    Huazhong Univ Sci & Technol Sch Mat Sci & Engn State Key Lab Mat Proc & Die & Mould Technol Wuhan 430074 Hubei Peoples R China;

    Huazhong Univ Sci & Technol Sch Mat Sci & Engn State Key Lab Mat Proc & Die & Mould Technol Wuhan 430074 Hubei Peoples R China;

    Huazhong Univ Sci & Technol Sch Mat Sci & Engn State Key Lab Mat Proc & Die & Mould Technol Wuhan 430074 Hubei Peoples R China;

    Huazhong Univ Sci & Technol Sch Mat Sci & Engn State Key Lab Mat Proc & Die & Mould Technol Wuhan 430074 Hubei Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Solid oxide fuel cell stack; Thermal cycling; Performance degradation; Post-test examination;

    机译:固体氧化物燃料电池堆;热循环;性能下降;测试后检查;

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