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Diffusion creen

机译:克里恩广播

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摘要

Diffusion creep refers to the phenomenon of flow on a surface along which is a concentration gradient. A number of well known mass transfer problems that have usually been analyzed ignoring diffusion creep are revisited, including isobaric and equimolar counterdiffu-sion, diffusion with one component stationary, and diffusion with surface reactions. The Kramers and Kistemaker model for the creep velocity is used as a benchmark, and the implications of more recent advanced kinetic theory analyses explored. The validity of Graham's law for isobaric counterdiffusion is examined. The resulting phenomenon of diffusiophoresis of Stokesian particles is briefly discussed.
机译:扩散蠕变是指表面上的流动现象,浓度梯度沿该现象发生。回顾了许多众所周知的传质问题,这些问题通常是在忽略扩散蠕变的情况下进行分析的,包括等压和等摩尔的反扩散,一种组分固定的扩散以及表面反应的扩散。蠕变速度的Kramers和Kistemaker模型用作基准,并探索了更先进的动力学理论分析的含义。检验了格雷厄姆定律对等压反扩散的有效性。简要讨论了由此产生的斯托克斯粒子的扩散电泳现象。

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