首页> 外文期刊>International journal of environmental analytical chemistry >INFLUENCE OF ORGANIC AMENDMENTS ON SORPTION AND DISSIPATION OF IMIDACLOPRID IN SOIL
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INFLUENCE OF ORGANIC AMENDMENTS ON SORPTION AND DISSIPATION OF IMIDACLOPRID IN SOIL

机译:有机物改良剂对咪唑洛比在土壤中的吸附和耗散的影响

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摘要

The effect of organic amendments (OA) on imidacloprid sorption and dissipation in soil was investigated. A sandy soil was treated at a rate of 10% w/w with three OA: one liquid (Liquid Fertiormont, LF) and two solid (Solid Fertiormont, SF, and Alperujo, A). Sorption was measured using a batch equilibration method. Dissipation studies in the dark were performed by incubating pesticide-treated soils at moisture content of — 0.33 KPa and 20 +- 2℃ for 28 days, whereas imidacloprid photolysis studies in soils were performed by irradiation of treated soils at water holding capacity in a Suntest apparatus with a xenon lamp for 32 h. In both cases, soils were sampled periodically and extracted for their imidacloprid content. Solid OA (SF and A) increased imidacloprid sorption by soils, whereas similar sorption was observed in soil amended with LF. Imidacloprid half-lives obtained from incubation studies in the dark remained unaffected upon amendment, whereas OA decreased the photolysis rate of imidacloprid in soils. However, no relation was observed between increase in sorption and decrease in the photodegradation rate of imidacloprid.
机译:研究了有机改性剂(OA)对吡虫啉在土壤中的吸附和消散的影响。用三种OA以10%w / w的速度处理砂土:一种液体(液体Fertiormont,LF)和两种固体(Solid Fertiormont,SF和Alperujo,A)。使用间歇平衡法测量吸附。在黑暗中的消散研究是通过在水分含量为-0.33 KPa和20 +-2℃的条件下将经过农药处理的土壤孵育28天而进行的,而吡虫啉在土壤中的光解研究则是通过在保水量最大的条件下辐照处理过的土壤进行的。带有氙气灯的装置32小时。在这两种情况下,均定期取样土壤并提取其吡虫啉含量。固体OA(SF和A)增加了吡虫啉对土壤的吸附,而在用LF改良的土壤中观察到了相似的吸附。修改后,在黑暗中孵育获得的吡虫啉半衰期保持不变,而OA降低了吡虫啉在土壤中的光解速率。然而,在吡虫啉的吸附增加与光降解速率降低之间未发现任何关系。

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