Designing and fabrication of a novel gold nanocomposite structure: application in electrochemical sensing of bisphenol A

摘要

In this article, a highly sensitive electrochemical sensor is introduced for direct electro-oxidation of bisphenol A (BPA). The novel nanocomposite was prepared based on multi-walled carbon nanotube/thiol functionalised magnetic nanoparticles (Fe3O4-SH) as an immobilisation platform and gold nanoparticles (AuNPs) as an amplifying electrochemical signal. The chemisorbed AuNPs exhibited excellent electrochemical activity for the detection of BPA. Some analysing techniques such as Fourier transform infrared spectroscopy, field emission scanning electron microscopy, transmission electron microscopy and energy-dispersive x-ray diffraction exposed the formation of nanocomposite. Under optimum conditions (pH 9), the sensor showed a linear range between 0.002-240M, with high sensitivity (0.25A M-1) along with low detection limit (6.73x10(-10) M). Moreover, nanocomposites could efficiently decrease the effect of interfering agents and remarkably enhance the utility of sensor at detection of BPA in some real samples.