Ionic liquid-modified silica-coated magnetic nanoparticles; promising anion-exchange sorbent for extraction of Cr(Ⅵ)

摘要

In the present study, ionic liquid-modified silica-coated magnetic nanoparticles (MNPs) were synthesised and applied as a new anion-exchange sorbent for extraction and determination of Cr(VI) followed by inductively coupled plasma atomic emission spectrometry. The characterisation of MNPs was carried out by scanning electron microscope, Fourier transform infrared and vibrating sample magnetometer. Experimental design and response surface methodology were used for optimisation of different parameters which affect extraction efficiency of Cr(VI). Under the optimised conditions, extraction recoveries within the range of 25-33% with relative standard deviations (RSD%, n = 4) within the range of 3.0-5.0% were obtained. The limit of detection was found to be 0.1 mu g L-1. The linearity was studied in the range of 0.5-200 mu g L-1 with the determination coefficient of 0.9958. Also, calculated Errors% for determination of Cr(VI) in the range of 5-15 depict that the method offers acceptable accuracy for analysis of Cr(VI). The method was successfully applied for extraction and determination of Cr(VI) selectively in some tannery waste water samples.