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Quadriphasic mechanics of swelling incompressible porous media

机译:膨胀不可压缩多孔介质的四相力学

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A chemo-electro-mechanical formulation of quasi-static finite deformation of swelling incompressible porous media is derived from mixture theory. The model consists of an electrically charged porous solid saturated with a monovalent ionic solution. Incompressible and isothermal deformation is assumed. Hydration forces are neglected. The mixture as a whole is assumed locally electroneutral. Four phases following different kinematic paths are defined: solid, fluid, anions and cations. Balance laws are derived for each phase and for the mixture as a whole. A Lagrangian form of the second law of thermodynamics is derived for incompressible porous media and is used to derive the constitutive relationships of the medium. It is shown that the theory is consistent with Biot's theory for the limiting case without ionic effects and with Staverman's results for the limiting case without deformation.
机译:溶胀不可压缩多孔介质的准静态有限变形的化学-机电公式是从混合理论推导出来的。该模型由充满一价离子溶液的带电多孔固体组成。假定不可压缩和等温变形。水合力被忽略。混合物总体上被认为是局部电子中性的。定义了遵循不同运动路径的四个阶段:固体,流体,阴离子和阳离子。得出每个阶段以及整个混合物的平衡定律。对于不可压缩的多孔介质,推导了热力学第二定律的拉格朗日形式,并用于推导介质的本构关系。结果表明,该理论与没有离子效应的极限情况的毕奥特理论是一致的,并且与没有变形的极限情况的斯瓦弗曼结果是一致的。

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