Study on the suitability of New Zealand coals for hydrogen production

摘要

Internationally there is considerable interest in utilizing hydrogen as an energy carrier. The use of hydrogen offers considerable potential benefits such as reducing greenhouse emissions, reducing urban pollution, increased energy security and increased efficiencies from the use of advanced energy conversion technologies. One of the most important questions when considering the development of a hydrogen economy is "where will the hydrogen come from?" Possible answers include electrolysis of water, steam reforming of methane and the gasification of coal. Given the high costs associated with electrolysis of water, and the increase in the cost of methane predicted over time, the gasification of coal is viewed by many as being the cheapest method of hydrogen production in the foreseeable future. These considerations are particularly relevant to New Zealand where gas supplies are dwindling but where there is sufficient coal to last for many centuries at present utilization rates. This, along with the current high international interest in hydrogen energy, has been recognized by the New Zealand Government in the form of a six-year [2002-2008] research project "Hydrogen Energy for the Future of New Zealand". One important coal property that, in particular, determines the suitability of a particular coal for use in a fluidised bed gasifier is its reactivity towards the gasification reaction. It was found that a high percentage of New Zealand's coal resource is particularly well-suited towards fluidised bed gasification, reacting at anywhere between 0.9 to 1.75 times the rate of Australian brown coals. It was found the New Zealand lignites contained significant levels of organically bound calcium, which was shown to be responsible for not only the high reactivity of the New Zealand lignites, but also a product gas composition with higher than expected hydrogen concentrations. These findings are discussed along with their implications for the gasifier and gas clean-up design.