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STB Model and Transport Properties of Pyrolytic Graphites

机译:热解石墨的STB模型和传输性质

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Structure and texture of pyrolytic graphites (PG) make it unlikely that the three dimensional electron-energy bands of ideal graphite would provide an adequate basis for a discussion of electron transport processes over a broad temperature range.1 We propose to demonstrate that a coherent description of PG layer-plane phenomena can be based on a parabolic two band system with cylindrical equal-energy surfaces, which are located around the vertical Brillouin zone edges. In this simple two-band model (STB model), band overlap and effective mass must be interpreted as phenomenological parameters to be derived from experiments on highly heat-treated pure PG; with p-type (boron doped) specimens, the objective is to describe the situation from the shift of the Fermi level, on the assumption that the presence of trapping centers would not inject major perturbations in the band structure.
机译:热解石墨(PG)的结构和质地使得理想石墨的三维电子能带不可能为讨论宽温度范围内的电子传输过程提供足够的基础。1我们建议证明一个连贯的描述PG层平面现象的产生可以基于具有圆柱等能量表面的抛物线两能带系统,该系统位于垂直的布里渊区边缘附近。在这个简单的两波段模型(STB模型)中,波段重叠和有效质量必须被解释为从高度热处理的纯PG实验中得出的现象学参数;对于p型(掺杂硼的)样品,目的是从费米能级的变化来描述情况,并假设存在俘获中心不会在能带结构中注入主要扰动。

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